|
When
this very proper product of Puritan New England moved west, he brought
essential chemistry to Caltech.
By Laura
Marcus
Laura
Marcuss last story for Caltech News was "A Caltech Couple:
Frank and Ora Lee Marble," in 1996. The present articleabout
the chemist of the triumvirate that created an institute of technology
in Pasadenacomes hot on the heels of an Institute professors
winning the Nobel Prize in chemistry. Ahmed Zewail, the Linus Pauling
Professor of Chemical Physics and professor of physics, accepted the prize
this December. The last Caltech chemist to win the prize was Rudy Marcus,
the Arthur Amos Noyes Professor of Chemistry, who happens to be Lauras
husband.
Caltech students
called him "the King"; some of his closest friends called him
Arturo; but most people knew him only as "Dr. Noyes," the scholarly,
quiet-spoken, and very reserved head of Caltechs chemistry department
(and later division) from 1919 until his death in 1936. In the famous
portrait of Caltechs Big Three, hes the one seated on the
left, beside Trustee George Ellery Hale, with Robert Millikan standing
between them.
Noyes was
a chemistry professor at MIT and its former acting president when Hale
persuaded him in 1913 to come on a part-time basis to Caltech, or Throop
College of Technology, as it was then known. (It changed its name to the
California Institute of Technology in 1920, about the same time that Noyeswho
had strongly advocated the name-changejoined the Institute permanently.)
When Hale was a student at MIT, he had taken a course with Noyes, who
was then a young instructor. Their respect for each others abilities
resulted in a teamwork that, combined with Robert Millikans truly
dynamic leadership, created the distinctive Caltech that we know today.
Professor
Noyes had very definite ideas about the best way to educate young men
to be scientists and engineers. He believed that classes should be small,
although he recognized the need for some large lecture courses. There
should be ample opportunity for faculty and students to interact, and
therefore a small, intellectually based institute was most desirable.
The faculty should be first-rate, of course.
It was Noyes
who initiated a Caltech core curriculum centered on strong fundamental
training in math and physics that remained essentially unchanged until
innovations were introduced in the last half of this decade. It was also
Noyes who insisted that the core requirements include a sizable number
of humanities coursesand that notable humanities scholars be recruited
to teach themso that undergraduates would spend roughly 20 percent
of their time studying literature, history, languages, government, and
economics. "The whole man" (one of his favorite concepts) needed
a well-rounded education.
Noyess
family background undoubtedly contributed to his views on education. His
father was a respected lawyer in the small town of Newburyport, Massachusetts,
where his ancestors had lived since 1635. The family was not particularly
prosperous, however, and because he could not afford to enter MIT for
his freshman year, Noyes studied at home the required subjects for freshmen
(except drawing). He enrolled as a sophomore the next year on a scholarship.
In high school
Noyes had found his chemistry teacher to be highly stimulating, so much
so that he and a friend set up a lab on the Noyes familys dining
room table. Unfortunately the experimental flask broke, spilling potash
and phosphorus over the table, the rug, and some of Mr. Noyess law
books. Thereafter, all the experiments in the textbook were attemptedbut
only in the Noyes family attic or in the friends barn.
When Noyes
finally did arrive at MIT, his college career was predictable. He received
his bachelors degree at the age of 19 in 1886 and an MS the next
year. He was then appointed assistant in analytical chemistry, teaching
qualitative analysis to a class of about 40 students. George Ellery Hale
was one of those students.
But Noyes
was eager for further training himself, and following the custom of the
time, he went to Europe to get it, receiving his PhD from the University
of Leipzig in 1890. Returning immediately to MIT as a faculty member,
he taught courses over the next decade in analytical, organic, and physical
chemistry, while actively conducting research with his students on the
ionic theory of electrolytes.
It was in
1903 at MIT that Noyes created and began directing the schools first
research laboratory for studies in pure sciencethe Research Laboratory
of Physical Chemistry, which trained many prominent chemists over the
years. Feeling so strongly about the importance of basic, creative research,
he paid one-half the laboratorys operating expenses from his personal
funds on a regular basis for 17 years, until his permanent departure for
Pasadena. During his last four years at MIT he directed the research at
that lab as well as the chemical research being done at Caltech.
He was able
to provide the MIT laboratorys financial support as a result of
a successful process he and W.R. Whitney, another MIT scientist, had developed
in the late 1890s. The process was designed to recover alcohol and ether
vapors which till then had been lost during the manufacture of photographic
films.
Noyes also
made his mark early as an author of scientific textbooks. First published
in 1892, his book on qualitative analysis was widely used in its many
revised editions, and became known as A Course of Instruction and System
of Procedure in the Qualitative Chemical Analysis of Inorganic Substances.
He also published (with coauthors) Laboratory Experiments on the Class
Reactions and Identification of Organic Substances (1898) and Qualitative
Analysis of the Rare Elements (1927), which he considered his most
important contribution to chemistry.
In 1914,
with his former student and fellow MIT faculty member Miles Sherrill,
Noyes published A Course of Instruction in the General Principles of
Chemistry. There followed a regular series of new editions and expansions,
which Sherrill continued after Noyess death. A landmark text in
the teaching of chemistry, it emphasized hands-on laboratory assignments,
ensuring that the student would avoid mere memorization. According to
Sherrill, Noyess work day usually ran from 4 a.m. till 8 p.m. Sometimes,
however, he took time off for a bike trip, oreven more to his likinga
sailing outing with some of his MIT colleagues. They used his 48-foot
yawl, Virginia, for summertime excursions along the New England coastNoyess
father had introduced him to boats and the fun of exploring nearby waterways
early on. Fortunately, a portion of the Virginia log has survived. Some
of the entries were made by a crew member named Richard Tolman, who would
later become a renowned Caltech professor of chemistry and physics.
The log does
not mention it, but another crew member has written that Noyess
students and friends were greatly impressed with his love of poetry and
his ability to recite "from memory by the hour with intonation and
diction never to be forgotten." Relaxing on a boat gave him that
opportunity.
The boating
life also made it possible to go over the side at 4:30 in the morning
for a wake-up swim, which was another of Captain Noyess special
pleasures. When he came to Caltech, however, he left his boat behind,
and although he bought a house at Corona del Mar on a cliff overlooking
the
Newport harbor, he never again bought anything larger than a canoe and
a rowboat, which were intended for visiting staff and students to use.
The boat
remained in Massachusetts, but Noyes did bring to Pasadena his firm conviction,
reinforced by years of teaching experience at MIT, that qualified undergraduates
should be introduced to research as soon as possible. Ideally, they should
be given a problem to work on directly with an instructor or in collaboration
with a more experienced student.
The late
Kenneth Pitzer, who at various times was research director of the Atomic
Energy Commission, a faculty member at UC Berkeley, and president of Rice
and Stanford Universities, remembered with appreciation the research assignment
he undertook at Caltech at the end of his freshman year in 1932 with graduate
student J. L. Hoard, under Noyess direction. The resulting paper,
entitled "Argentic Salts in Acid Solutions. I," was published
with Noyes as a coauthor. That paper helped to prepare the way for Pitzers
illustrious career. Other students benefited from similar experiences.
Always on
the alert for the brightest, most promising students, Noyes spotted William
Pickering soon after the enterprising sophomore from New Zealand arrived
at Caltech in 1929 intending to study engineering. Encouraged by both
Noyes and Millikan to switch to science, Pickering did so, and stayed
on to receive his PhD in physics in 1936. He became a Caltech professor
and for 22 years was director of the Jet Propulsion Laboratory.
Today, Pickering,
now 89, recalls how, to fulfill a sophomore chemistry requirement, he
and four other students were invited to spend the summer in Corona del
Mar, where they were given a course by professor Ernest Swift, who also
had a summer home there. The students lived at Caltechs marine lab,
a former boathouse that had just been bought by Caltech at Noyess
behest when the neighboring yacht club hit hard times. Noyes had made
an arrangement with renowned Caltech biologist Thomas Hunt Morgan that
allowed him to use an upstairs space for chemical research, bringing down
a graduate student and two or more honors undergraduates to work there
during the summers on problems in analytical chemistry. A wooden stairway,
built by young professor Arnold Beckman and handyman Hal Weis, connected
the marine lab to Noyess property on the cliff. Although Pickering
did not see Noyes there, he later learned that the special opportunity
had been made possible by him.
For Pickering
another special treat came in 1931 during his junior year at Caltech,
when he and Charles Jones received the travel grants awarded
annually by an anonymous donor to two outstanding juniors. (Two other
students were invited to join them at their own expense.) A new Ford,
picked up at the Detroit plant, was made available for their six months
of travel in Europe. To make sure they were properly prepared for their
cultural adventure, they had been enrolled the previous term in a class
taught by
Professor John Macarthur, a Caltech humanities professor. Upon their return
to Pasadena, they were only asked to give an account of their experiences
at one of the weekly student assemblies.
Professor
Noyes, an enthusiastic traveler himself, was generally acknowledged to
be the anonymous chief sponsor of the travel grant. His gesture reflected
once again his belief that well-trained scientists and engineers needed
a broad exposure to the humanities and liberal arts.
Noyes was
himself a member of the close-knit American Philosophical Society, founded
in 1734 in Philadelphia by Benjamin Franklin and other proponents of the
Enlightenment. And he was predictably also very active in scientific organizations.
In 1916, he, Hale, and Millikan helped to set up the National Research
Council to assist the National Academy of Sciences in advising the government
on scientific issues. During World War I he served as NRC chairman. Many
young menand Caltech itselfbenefited from that organization
through the prestigious annual fellowships it awarded. A number of Caltech
faculty members came to campus initially as National Research Council
Fellows, while others held those fellowships at Caltech before going on
to other universities.
In fact,
long before coming to Caltech, or to Throop College of Technology, as
it was then known, Noyes was nationally recognized as a leading scientist.
As early as 1895, he had established and edited the journal Review
of American Chemical Research, and then watched it grow into the invaluable
Chemical Abstracts, an ongoing record of chemical research. In
1904, at the age of 38, Noyes was elected president of the American Chemical
Society, the youngest man to hold that office. A year later, he was elected
to the National Academy of Sciences, and went on to serve as editor of
its Proceedings in 191516. Later he served as president of
the American Association for the Advancement of Science. Recognition of
his own research contributions culminated in such honors as the Humphry
Davy Medal of the Royal Society of London (1927), the Willard Gibbs Medal
of the Chicago Section of the American Chemical Society (1915), and the
Theodore William Richards Medal of the Northeastern Section of the American
Chemical Society (1932), which named him as its first recipient. He also
received honorary degrees from Harvard, Yale, and several other institutions.
Although
he held national offices and enjoyed an international reputation, Noyes
was happiest as a teacher and scientist. The most capable students, his
"carefully selected seeds," were singled out, but he also concentrated
on building the best faculty and research organization possible. A number
of young men contributed to his reaching that goal.
Arnold Beckman
had completed his undergraduate and masters degrees at the University
of Illinois before following Professor Richard Tolman to Caltech. A student
of Noyes at MIT, Tolman was teaching at Illinois when Noyes lured him
to Pasadena in 1921.
Beckman liked
the idea of coming west, too, and arrived at Caltech in 1924. But after
being in the Institutes graduate program for one year, Beckman took
a trip back east to visit his girlfriend, Mabel Meinzer, and decided to
accept a research job at the Western Electric Engineering Company (later
called Bell Labs), where a college friend was already working. After a
year there, Arnold and Mabel were married, and were happily immersed in
their new life when Professor Noyes came to New York.
"Dont
you want to come back and finish your degree?" Noyes asked Beckman.
He did, and the rest is historyhis contributions as a faculty member,
highly successful inventor and entrepreneur, Caltech trustee chair, and
long-term benefactor to the Institute.
Linus Pauling
came down from Oregon in September 1922 with a fellowship to enter Caltechs
graduate program in chemistry. He had already received a letter from Noyes
that suggested how he could strengthen his physical chemistry background
before his arrival. Accordingly, Pauling had used his spare time that
summer, while employed on a road-paving project, to work all the problems
from the proof sheets of Chemical Principles, which Noyes and Sherrill
were then in the process of issuing in a new edition. Upon receiving his
PhD in 1925, Pauling went to Munich on a Guggenheim grant. While in Europe
he had Noyess financial assistance when needed.
After returning
to Caltech as assistant professor of theoretical chemistry, Pauling built
a large research group, with emphasis on crystallographic techniques for
studying a variety of problems. His vitality and wide-ranging intellect
made him a major figure in 20th century science, and he was awarded the
Nobel Prize in 1954 for his work on the nature of the chemical bond. After
Noyess death, Pauling became chairman of the Division of Chemistry
and Chemical Engineering at Caltech, a position he held from 1937 till
1958.
The field
of X-ray diffraction had been a focus of research in the chemistry department
ever since Noyess arrival, and the Institute was recognized as the
outstanding center for that work. Noyes had early recognized the importance
of the new field of X-ray crystallography and he encouraged his former
MIT graduate student C. L. Burdick (who was doing postdoctoral research
in Europe) to go and study with William Bragg (a future Nobel laureate)
in London. Burdick took Noyess advice, and, later, when he joined
Noyes at Caltech, he did pioneering work in that specialty.
Noyes was
constantly on the alert for new developments and new experiments under
way in England or on the continent, and equally vigilant about sending
his people there to learn about them so that they could bring that expertise
back to Caltech. Among the people he brought from MIT was his graduate
student Roscoe Dickinson, who immediately started his research in X-ray
crystallography. The first PhD Caltech awarded was to chemist Dickinson
in 1920.
Another of
Noyess future mainstays came out on the train with him as a new
graduate student in 1919. Ernest Swift had met Noyes at the University
of Virginia and had sought his advice about graduate study. Noyess
"advice" was to accept Swift on the spot for Caltech and to
offer him a teaching fellowship (later called assistantship). On the long
trip west, Swift later recalled, there was not much talk about chemistry
but a lot of bridge-playing, with both Noyes and his MIT student James
Ellis, who was also traveling with him.
Noyes was
revising his textbook on qualitative analysis and solicited Swifts
help in testing the experimental procedures being used in the book. One
summer he also asked Swift to teach an intensive course to a group of
about 20 undergrads, in order to push them along toward their junior and
senior requirements. Swift belatedly learned that Noyes had personally
paid his salary for teaching that course.
During Swifts
second year at Caltech, an instructor position opened in the sophomore
chemistry course that he had been assisting in, and, to this young graduate
students immense surprise, Noyes asked if he would like to teach
the course. Ultimately, Swift would succeed Pauling as division chairman,
serving from 1958 to 1963.
Along with
his prowess in chemistry, Swift was an accomplished tennis playereven
after his retirement in 1967, it was generally conceded that he was still
the man to beat on the court. Noyes played him only once, Swift said,
adding that "he never really was a robust physical specimen at all.
Always kind of gaunt, moved slowly and talked slowlyexceedingly
formal. I dont remember his ever once addressing me by anything,
after I got my degree, but Dr. Swift."
Despite his
formal manner, Noyes liked to invite his students and coworkers to join
him on outings, no longer by boat but by car, which he drove out to the
desert or to Corona del Mar.
 |
In
this 1917 photo, Noyes sits in the drivers seat of the Cadillac
touring car given him by George Ellery Hale. In Pasadena, Noyes drove
Techers around and relied on their technical skills to keep the car
running somewhat smoothly. |
George Ellery
Hale had given Noyes his Cadillac touring car, and it was in this vehicle
that Noyes and his two Irish maids drove to Pasadena from Boston. His
students named the car "Mossie," short for Demosthenes, because
of its stuttering habits. Not an expert driver, Noyes would sometimes
try to start off in second gear or fail to use the choke properly. His
passengers would be called upon to solve various mechanical problems,
which in turn supplied them with lasting anecdotes.
In his early
days at Caltech, Noyes was the chemists admissions committee, sizing
up the candidates in person or by letter, and readily accepting likely
ones. He often met newcomers at the railroad station and helped to make
arrangements for their living accommodations. He also firmly held the
purse strings for their support. With his and Hales longstanding
ties to the East Coast scientific establishment, Noyes had ongoing support
from such institutions as the Carnegie Institution of Washington, which
between 1920 and 1930 funded 20 projects under Noyess direction
in the Gates Laboratory of Chemistry. By 1930 the Gates Lab had published
269 research papers.
Noyes had
been promised a laboratory when he agreed to move to Caltech, and, with
the building of Gates in 1917, his dream of having a modern chemical-research
laboratory had come true. But within a decade he was complaining that
there was absolutely no more space available in the lab for additional
researchers. Investigations had grown to encompass not only physical chemistry
but also biochemistry, organic chemistry, and industrial chemistrythe
latter, when specific projects were approved.
The need
for more space eventually led to the addition of a western wing to Gates,
and in 1937, a year after Noyess death, to the construction of Crellin
Laboratory. In 1967, yet another chemistry building, the Arthur Amos Noyes
Laboratory of Chemical Physics, was added to the campus.
Although
Noyes was closely involved in divisional activities and in the making
of policy, he believed in sharing the decision-making process, as evinced
in a memo he wrote entitled "A Plan for Bringing Younger Faculty
Members Outstanding in Research or Education into Contact with the Problems
and Ideals of the Institute." His plan was to set up a policy advisory
committee that would be appointed by the executive council, "and
directly responsible to it," with members to serve for two-year terms,
"with privilege of reappointment." The 12 representatives he
suggested for the initial membership were drawn from physics, mathematics,
engineering, chemistry, geology, and biology. Within the chemistry department,
he divided up administrative responsibilities and used committees extensively
for cooperative planning and research.
In his mission
he had one superb allyGeorge Ellery Hale. Hale and Noyes shared
the same philosophy of education and the same goals, and they worked well
together.
As a private
institution, Caltech had to attract a lot of moneyfrom
the trustees, from scientific foundations, from prosperous friends wherever
they were. It was a constant, never-ending pursuit, and Hale, Millikan,
and Noyes bore the greatest responsibility as they tried to attract the
best for the least amount of money possible. During the difficult Depression
years, Noyes gave freely from his own pocket for salaries, prizes, special
student events, and research support. When he died he left his fine Corona
del Mar house to the Institute. His Pasadena house on San Pasqual, close
to campus, was bought by another Caltech chemist, Don Yost.
In spite
of painful health problems during the last decade of his life, Noyes held
to his rigorous work schedule as much as possible, chairing the division
and publishing revisions to his textbooks. Days before he was scheduled
to go to the Mayo Clinic for surgery, he was writing letters on Institute
matters. He kept a cot in his office for occasional use. Less than two
months after the surgery, he died back in Pasadena of pneumonia, in June
1936, shortly before his 70th birthday.
Noyes, who
never married, left the proceeds of his estate to Caltech for the support
of research in chemistry. Later, the Arthur Amos Noyes Professorship was
established.
In addition
to the Noyes building on the Caltech campus, there is another local building
that bears his name. It is the Arthur Amos Noyes School, an elementary
school dedicated in 1954 on Pinecrest Drive in Altadena.
The Caltech
campus itself holds another mementoNoyess handsome grandfather
clock, which now resides in the office of Chemistry and Chemical Engineering
Division Chair David Tirrell. And in Arnold Beckmans home in Corona
del Mar, a small chair belonging to Noyes, rescued and repaired by Beckman,
has a place of honor.
After Noyes
died, two of his old friends at CaltechRichard Tolman and William
Laceyagreed that possibly his greatest achievement lay in founding
the science of physical chemistry in America. And Robert Millikan commented
on Noyess contributions to Caltech beyond chemistry by saying: "He
spent more time than any other man on the campus trying to create here
outstanding departments of physics, of mathematics, of the humanities,
of geology, of biology, and of the various branches of engineering; and
what these departments are today they owe, more than they themselves know,
to Arthur A. Noyes."
The Caltech
Board of Trustees gave Noyes this tribute:
From 1919 until his death in 1936, Dr. Noyes was the most constructive
influence in the development of the educational policies of the California
Institute and in shaping its ideals and its program. . . . There has
been no more significant figure in the development of chemistry in the
United States than Arthur A. Noyes. The imprint which he made on both
the two institutions at which he spent his life, the Massachusetts Institute
of Technology and the California Institute of Technology, have been
far reaching and lasting. . . . His extraordinary soundness of judgment,
unselfish devotion to science, sweetness of character, thoroughness
of analysis, and objectivity of approach made him an unmatched leader
in every undertaking to which he devoted his energies.
Only one
characteristic seems to be missing from this eulogy. He was said by his
friends to have a good sense of humor, even a dry wit. Too bad he couldnt
have heard all the compliments paid him. The only trouble is, he would
undoubtedly have been greatly embarrassed by them. "A. Noyes annoys
A. Noyes," he was overheard to say on at least one occasion.
But not too
frequently, one hopes.
Sources:
The following people who were at Caltech when Dr. Noyes was here were
interviewed by this writer (those who are now deceased are indicated by
an asterisk): Albert Atwood, Jr.*, Arnold Beckman, James Bonner*, Joseph
Koepfli, William Pickering, Kenneth Pitzer*, Robert Sharp, Verner Schomaker*,
and Vito Vanoni. Other sources were the Noyes file in the Caltech Archives,
and the Caltech
Archives oral histories of Beckman, Koepfli, Ernest Swift, and Oliver
Wulf. My special thanks to Bonnie Ludt in the Archives, Pat Bullard in
the chemistry division office, and Arnold Beckmans daughter, Pat.
Professor John Waugh of MIT supplied a copy of the Virginia log. University
Archivist Judith Goodsteins Millikans School is an
essential source for anyone interested in Caltech history. Among other
useful sources was the detailed article on Noyes written by Linus Pauling
and published in the Biographical Memoirs of the National Academy of Sciences
in 1958.
|